Business units are hierarchical groupings of staff which can be used to define groups by location, (for example, the New York office), function, (for example, Sales Department), and so on

A Job is a general classification for set of functions and/or tasks. E.g. Manager.

A position is a specific entity occupied by holder(s) and attached to a Business unit. Position is described by a job, and hence a position automatically inherits the tasks and characteristics assigned to a job. E.g. Human Resource Manager.
Note: Jobs are not designed to be held by employees. This is the role of a position.

Tasks describe the work responsibilities of jobs and positions. E.g. Sales Manager determines sales quotas.

Work center is the specific, physical work location where a single job or single position's tasks are performed regardless the number of employees. A work center can represent anything as general as a geographical location, such as the Philadelphia branch office. Or they can be very precisely defined, such as a particular workstation with specific equipment. Examples of work centers could be a reception area where 2 receptionist positions are located.

The budget centre to which position is attached. E.g. Bank.